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Fe 3+ is reduced to a greater extent in H 2 /N 2 (1/99) than in CO/CO 2 (98/2), even though the CO partial pressure is much higher than that of H 2. This is explained by the faster permeation rate of a H 2 molecule due to its smaller size.

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Sep 27, 2018 · Amongst NH3 , PH3 , AsH3 and SbH3 the one with highest boiling point is : (A) NH3 because of lower molecular weight (B) SbH3 because of higher molecular weight (C) PH3 because of H-bonding (D)AsH3 because of lower molecular weight 57.

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(ii) Arrange NH3, PH3, AsH3, SbH3, BIH3 in order of increasing acidic strength. (iii) Why do noble gases form compound with oxygen and fluorine only ? (iv) Write balanced equation for the following : (a) NaCl is heated with sulphuric acid in presence of MnO2. (b) Cl2 gas is passed into a solution of NaI in water. 5. Q. 29.

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H2O HF H2Te H2Se NH3 SbH3 H2S HI AsH3 HCl HBr PH3 100 Boiling Points 0ºC -100 200. Hydrogen Bonding • Very strong dipole-dipole forces exist when H is attached to F, O, or N • Strictly between a molecule with Hydrogen and another molecule with F, O, or N in it. • Use dotted line to indicate hydrogen bonding.

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From the Wikipedia article for phosphine:. The low dipole moment and almost orthogonal bond angles lead to the conclusion that in PH3 the P-H bonds are almost entirely pσ(P) – sσ(H) and phosphorus 3s orbital contributes little to the bonding between phosphorus and hydrogen in this molecule.

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Short wavelength photons (of energy much greater than Eg ) create ‘‘hot’’ carriers. If, somehow, thermalization of these carriers can be avoided, photoelectrochemical reactions that would otherwise be impossible with the ‘‘cooled’’ counterparts, that is, at very negative potentials for n-type semiconductors, would be an ...

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(a) Less than 109.5º (b) 109.5º (c) Greater than 109.5º but less than 120º (d) 120º (e) Greater than 120º 5. Consider the bonds labeled iv and v. Which of the following statements is true? (a) v has a larger bond energy and has a higher vibrational frequency than iv. (b) v has a larger bond energy than iv, and they have the same ...

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Greater reliance is placed on molecular structure in developing subsequent topics (for example, acid–base equilibria, chemical kinetics, electrochemistry, organic chemistry, and the chemistry of transition metal complexes) than in the sixth edition.

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PH3 is a trigonal pyramidal molecule with C3v molecular symmetry. The length of the P-H bond 1.42 Å, the H-P-H bond angles are 93.5°. The dipole moment is 0.58 D, which increases with substitution of methyl groups in the series: CH3PH2, 1.10 D; (CH3)2PH, 1.23 D; (CH3)3P, 1.19 D.
VSEPR: VSEPR stands for valence shell electron pair repulsion, which is a theory that predicts the shape of molecules. The shape of molecules depends on how many atoms are in the compound and how ...
Arrange the group 5A hydrides PH3, SbH3, NH3, and AsH3 from highest to lowest molar mass. Highest to lowest - SbH3, AsH3, PH3, and NH3 Step 3: The boiling point of a compound increases with an increase in molar mass.
Polar Molecules: The Influence of Molecular Geometry Molecular geometry affects molecular polarity. Due to the effect of the bond dipoles and how they either cancel or reinforce each other. Polarity By adding the individual bond dipoles, one can determine the overall dipole moment for the molecule.
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covalent ____ 14. COS has a dipole moment because it is asymmetric and the dipole moments do not completely cancel. Van der Waals' forces are weaker in PH3 than in NH3. Eneg of C = 2. Van der Waals forces are weaker in PH3 then in NH3. interactions hydrogen bonds.
From the Wikipedia article for phosphine:. The low dipole moment and almost orthogonal bond angles lead to the conclusion that in PH3 the P-H bonds are almost entirely pσ(P) – sσ(H) and phosphorus 3s orbital contributes little to the bonding between phosphorus and hydrogen in this molecule.